A-Level Chemistry Specification

Edexcel 9CH0

Section 8: Energetics I

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#8.1

know that standard conditions are 100 kPa and a specified temperature, usually 298 K

#8.2

know that the enthalpy change is the heat energy change measured at constant pressure

#8.3

be able to construct and interpret enthalpy level diagrams showing an enthalpy change, including appropriate signs for exothermic and endothermic reactions

Activation energy is not shown in enthalpy level diagrams but it is shown in reaction profile diagrams.

#8.4

be able to define standard enthalpy change of:

i) reaction
ii) formation
iii) combustion
iv) neutralisation

#8.5

understand experiments to measure enthalpy changes in terms of:

i) processing results using the expression:

energy transferred = mass × specific heat capacity × temperature change
(Q=mcΔT)

ii) evaluating sources of error and assumptions made in the experiments

Students will need to consider experiments where:
- substances are mixed in an insulated container and the temperature change is measured
- enthalpy of combustion is measured, such as using a series of alcohols in a spirit burner
- the enthalpy change cannot be measured directly.

#8.6

be able to calculate enthalpy changes in kJ mol-1 from given experimental results

Both a sign and units are expected in the final answer.

#8.7

be able to construct enthalpy cycles using Hess’s Law

#8.8

be able to calculate enthalpy changes from data using Hess’s Law

#8P8

CORE PRACTICAL 8: To determine the enthalpy change of a reaction using Hess’s Law

#8.9

know what is meant by the terms ‘bond enthalpy’ and ‘mean bond enthalpy’

#8.10

be able to calculate an enthalpy change of reaction using mean bond enthalpies and explain the limitations of this method of calculation

#8.11

be able to calculate mean bond enthalpies from enthalpy changes of reaction