A-Level Chemistry Specification

OCR A H432

Section 6.1.3: Carboxylic acids and esters

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#6.1.3a

explanation of the water solubility of carboxylic acids in terms of hydrogen bonding

#6.1.3b

reactions in aqueous conditions of carboxylic acids with metals and bases (including carbonates, metal oxides and alkalis)

Comparison of acidity of different carboxylic acids not required.
PAG7 (see 6.3.1c)

#6.1.3c

esterification of:

(i) carboxylic acids with alcohols in the presence of an acid catalyst (e.g. concentrated H2SO4)
(ii) acid anhydrides with alcohols

#6.1.3d

hydrolysis of esters:

(i) in hot aqueous acid to form carboxylic acids and alcohols
(ii) in hot aqueous alkali to form carboxylate salts and alcohols

#6.1.3e

the formation of acyl chlorides from carboxylic acids using SOCl2

#6.1.3f

use of acyl chlorides in synthesis in formation of esters, carboxylic acids and primary and secondary amides.

Including esterification of phenol, which is not readily esterified by carboxylic acids.