A-Level Chemistry Specification

OCR A H432

Section 3.1.4: Qualitative analysis

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#3.1.4a

qualitative analysis of ions on a test-tube scale; processes and techniques needed to identify the following ions in an unknown compound:

(i) anions:
- CO32–, by reaction with H+(aq) forming CO2(g) (see 2.1.4c)
- SO42–, by precipitation with Ba2+(aq)
- Cl, Br, I (see 3.1.3g)

(ii) cations: NH4+, by reaction with warm NaOH(aq) forming NH3.

Sequence of tests required is carbonate, sulfate then halide. (BaCO3 and Ag2SO4 are both insoluble.)
PAG4