A-Level Chemistry OCR A H432

3.1.4: Qualitative analysis

#3.1.4a

qualitative analysis of ions on a test-tube scale; processes and techniques needed to identify the following ions in an unknown compound:

(i) anions:

  • CO32–, by reaction with H+(aq) forming CO2(g) (see 2.1.4c)
  • SO42–, by precipitation with Ba2+(aq)
  • Cl, Br, I (see 3.1.3g)

(ii) cations: NH4+, by reaction with warm NaOH(aq) forming NH3.

Sequence of tests required is carbonate, sulfate then halide. (BaCO3 and Ag2SO4 are both insoluble.) PAG4

3.1.3
The halogens
3.2.1
Enthalpy changes