A-Level Chemistry AQA 7405

1.10: Equilibrium constant Kp for homogeneous systems

#1.10.1

The equilibrium constant Kp is deduced from the equation for a reversible reaction occurring in the gas phase.

Kp is the equilibrium constant calculated from partial pressures for a system at constant temperature.

Students should be able to:

  • derive partial pressure from mole fraction and total pressure
  • construct an expression for Kp for a homogeneous system in equilibrium
  • perform calculations involving Kp
  • predict the qualitative effects of changes in temperature and pressure on the position of equilibrium
  • predict the qualitative effects of changes in temperature on the value of Kp
  • understand that, whilst a catalyst can affect the rate of attainment of an equilibrium, it does not affect the value of the equilibrium constant.
1.9
Rate equations
1.11
Electrode potentials and electrochemical cells