IB Chemistry HL 100113

Reactivity 1.1: Measuring enthalpy changes

#Reactivity 1.1.1

Chemical reactions

Chemical reactions involve a transfer of energy between the system and the surroundings, while total energy is conserved.

Understand the difference between heat and temperature.

#Reactivity 1.1.2

Endothermic and exothermic reactions

Reactions are described as endothermic or exothermic, depending on the direction of energy transfer between the system and the surroundings.

Understand the temperature change (decrease or increase) that accompanies endothermic and exothermic reactions, respectively.

#Reactivity 1.1.3

Energy profiles

The relative stability of reactants and products determines whether reactions are endothermic or exothermic.

Sketch and interpret energy profiles for endothermic and exothermic reactions.

Axes for energy profiles should be labelled as reaction coordinate (xx), potential energy (yy).

#Reactivity 1.1.4

Standard enthalpy change of reaction

The standard enthalpy change for a chemical reaction, ΔHΔH^{⦵}, refers to the heat transferred at constant pressure under standard conditions and states. It can be determined from the change in temperature of a pure substance.

Apply the equations Q=mcΔTQ = mcΔT and ΔH=QnΔH = -\dfrac{Q}{n} in the calculation of the enthalpy change of a reaction.

The units of ΔHΔH^{⦵} are kJ mol-1.

The equation Q=mcΔTQ = mcΔT and the value of cc, the specific heat capacity of water, are given in the data booklet.

Structure 3.2
Functional groups: Classification of organic compounds
Reactivity 1.2
Energy cycles in reactions